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Gasphasenphotokatalyse: Totaloxidation von Kohlenwasserstoffen mit verschiedenen Oxidationsmitteln und selektive Stickstoffoxidreduktion an Titandioxid

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Description

Der Einfluß der Katalysatortemperatur, der Lichtwellenlänge, der Bestrahlungsstärke und der Zusammensetzung der Reaktionsmischung auf die Geschwindigkeit der photokatalytischen Totaloxidation kurzkettiger Kohlenwasserstoffe wird dargestellt. Als Oxidationsmittel dienen O2, NO2, und Mischungen aus NO2 und O2 sowie NO und O2. Der Reaktionsweg einer selektiven photokatalytischen NO-Reduktion zu N2 mit Kohlenwasserstoffen als Reduktionsmittel in einer sauerstoffreichen Atmosphäre wird aufgeklärt. Als Katalysatormaterial dient nanokristalliner Anatas, weitere Katalysatorproben wurden durch Kugelmahlen von mikrokristallinen Rutil- und Anatas-Ausgangsmaterialien hergestellt. Die Reaktionsgeschwindigkeit im stationären Zustand wird in einem Photoreaktor mit der Verweilzeitverteilung eines idealen Durchflußrührkessels bestimmt. Aus dem Quotienten aus Reaktionsgeschwindigkeit und Photonen-Absorptionsgeschwindigkeit der Katalysatorproben werden Quantenausbeuten errechnet. Aufgrund der experimentellen Ergebnisse wird ein katalytischer Kreis vorgeschlagen, in dem Sauerstoffdefekten im TiO2 die Rolle der aktiven Zentren zukommt.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
20 August 2009
Listed Since
10 December 2009

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