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Südwestdeutscher Verlag für Hochschulschriften Strukturkontrollierte Synthese: von verzweigten und linearen Oligo- und Polysilanen mit neuartigen Katalysatorsystemen

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Description

von verzweigten und linearen Oligo- und Polysilanen mit neuartigen Katalysatorsystemen. In dieser Arbeit konnte gezeigt werden, dass sich die von Rieger et al. bereits erfolgreich für die Olefinpolymerisation erprobten „Dual-Side“ Metallocene auch für die Dehydrokupplung von Hydrosilanen eignen. Es zeigte sich, dass Zirkonocene mit einem sterisch moderaten Anspruch der Ligandensphäre die besten Ergebnisse liefern. Des Weiteren wurde im Rahmen dieser Arbeit eine neue Synthesemethode für verzweigte Polysilane erschlossen. Es stellte sich heraus, dass lewisacide Borverbindungen im Stande sind, bei erhöhter Temperatur Phenylsilan zu polymerisieren und, dass dabei auch Alkylsilane in das Polymer eingebaut werden können.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
18 October 2011
Listed Since
19 October 2011

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