LAP Lambert Academic Publishing N-alkilirovannye aromaticheskie aminy: Sintez vtorichnykh alkilarilaminov i izuchenie ikh reaktsionnoy sposobnosti v arensul'fonilirovanii

Provedeno gidrogenizatsionnoe aminirovanie nekotorykh al'degidov alifaticheskogo ryada aromaticheskimi aminami i arensul'fonilirovanie poluchennykh zhirnoaromaticheskikh aminov. Sdelan vyvod o tselesoobraznosti sovmeshcheniya sinteza N-alkilanilinov s polucheniem ikh sul'fonil'nykh proizvodnykh, t. k. pri etom ne nuzhno provodit' vydelenie i dopolnitel'nuyu ochistku amina, chto pozvolyaet sokratit' stadii polucheniya sootvetstvuyushchikh sul'fonamidov. Sistematicheski izucheno poluchenie ryada N-alkilaromaticheskikh aminov vosstanovitel'nym aminirovaniem alifaticheskikh al'degidov anilinom i ego monozameshchennymi v aromaticheskom kol'tse v prisutstvii katalizatora Pd/C. Issledovano vliyanie stroeniya reagentov i rastvoritelya na kinetiku reaktsii N-alkilanilinov s arensul'fonilkhloridami. Opredeleny aktivatsionnye parametry dannoy reaktsii. Provedeny raschety energeticheskikh, elektronnykh i geometricheskikh kharakteristik molekul vtorichnykh zhirnoaromaticheskikh aminov i arensul'fonilkhloridov s tsel'yu ob"yasneniya reaktsionnoy sposobnosti izuchaemykh aminov v arensul'fonilirovanii. About the Author Sterlikova Irina Olegovna – kandidat khimicheskikh nauk, IvGU, programmist biologo-khimicheskogo fakul'teta,Ivanovo; Klyuev Mikhail Vasil'evich – doktor khimicheskikh nauk, IvGU, zaveduyushchiy kafedroy organicheskoy i biologicheskoy khimii,Ivanovo; Kustova Tat'yana Petrovna – doktor khimicheskikh nauk, IvGU, professor kafedry organicheskoy i biologicheskoy khimii,Ivanovo.