Synthesis of Substituted Butenolides and Related Natural Products: Stereoselective Vinylogous Aldol Reaction of Tetronamides and the Synthesis of Rubrolides and β-Substituted Butenolides - Image 1

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LAP Lambert Academic Publishing Synthesis of Substituted Butenolides and Related Natural Products: Stereoselective Vinylogous Aldol Reaction of Tetronamides and the Synthesis of Rubrolides and β-Substituted Butenolides

Name: Synthesis of Substituted Butenolides and Related Natural Products: Stereoselective Vinylogous Aldol Reaction of Tetronamides and the Synthesis of Rubrolides and -Substituted Butenolides
Brand: LAP Lambert Academic Publishing
Price: 61.0 GBP
Availability: InStock

Organic Chemistry

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Description

Butenolides are α,β-unsaturated lactone and are found in many natural and unnatural products with diverse biological properties. Owing to the prevalence of the substituted butenolides, much effort has been directed towards developing efficient methodologies for their synthesis and transformations. Among them, stereoselective access of the γ-substituted butenolide derivatives by utilizing the concept of vinylogy, which usually involves the carbon–carbon formation with an appropriate electrophile at the γ-position of butenolides, has triggered increasing interest. This thesis presents an efficient, simple, scalable and direct stereoselective vinylogous aldol reaction of β-aminosubstituted butenolides (tetronamides) with aldehydes. In addition, this thesis also describes the total syntheses of butenolide core bearing marine natural metabolites, rubrolides by using a highly regioselective late-stage bromination strategy from appropriate intermediates, and apprises a facile reductive dehalogenation of α-halo-β-substituted butenolides.

Product Specifications

Brand: LAP Lambert Academic Publishing
Format: paperback
ASIN: 6136596628
Category: Books > Subjects > Science, Nature & Maths > Chemistry > Organic Chemistry
Domain: Amazon UK
Release Date: 16 January 2018
Listed Since: 26 January 2018

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LAP Lambert Academic Publishing Synthesis of Substituted Butenolides and Related Natural Products: Stereoselective Vinylogous Aldol Reaction of Tetronamides and the Synthesis of Rubrolides and β-Substituted Butenolides

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It has never been this cheap. We have no record of a lower price.

LAP Lambert Academic Publishing Synthesis of Substituted Butenolides and Related Natural Products: Stereoselective Vinylogous Aldol Reaction of Tetronamides and the Synthesis of Rubrolides and β-Substituted Butenolides

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