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LAP Lambert Academic Publishing Stability & aging studies of Pr-based nickelates as cathodes for SOFC

Name: Stability & aging studies of Pr-based nickelates as cathodes for SOFC
Brand: LAP Lambert Academic Publishing
Price: 64.0 GBP
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Chemistry

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Description

This book is dedicated to stability and ageing studies of Praseodymium based nickelates as cathodes for Solid Oxide Fuel Cells (SOFCs). With this respect Ln2NiO4+δ (Ln=La, Pr or Nd) compounds with the K2NiF4 type structure act as alternative cathode materials for IT-SOFC due to their mixed ionic and electronic conductivity (i.e. MIEC properties). Pr2NiO4+δ shows excellent electrochemical properties at intermediate temperature (i.e. low polarization resistance Rp value, Rp = 0.03 Ω.cm² at 700 °C), while La2NiO4+δ exhibits higher chemical stability. So, the properties of La2-xPrxNiO4+δ nickelates were investigated with the aim to find best compromise between chemical stability and electrochemical performances. As an interesting point, even after complete dissociation of Pr2NiO4+δ into PrNiO3-δ, Pr4Ni3O10+δ and Pr6O11, the polarization resistance does not show significant change. So finally, two new materials PrNiO3-δ and Pr4Ni3O10+δ were investigated as SOFCs cathode showing very promising results for Pr4Ni3O10+δ in symmetrical cell (Rp (Pr4Ni3O10+δ) = Rp (Pr2NiO4+δ) = 0.15 Ω.cm² at 600 ° C) and single cell (1.6 W.cm-2 at 800 °C).

Product Specifications

Brand: LAP Lambert Academic Publishing
Format: paperback
ASIN: 3659977306
Category: Books > Subjects > Science, Nature & Maths > Chemistry
Domain: Amazon UK
Release Date: 16 December 2016
Listed Since: 09 January 2017

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LAP Lambert Academic Publishing Stability & aging studies of Pr-based nickelates as cathodes for SOFC

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