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LAP Lambert Academic Publishing Novye sintezy fosfororganicheskikh soedineniy na osnove krasnogo fosfora: Razrabotka udobnykh metodov sinteza organicheskikh fosfinov i fosfinkhal'kogenidov

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Description

V nastoyashchee vremya vse bol'shee vnimanie udelyaetsya "beskhlornym" metodam sinteza fosfororganicheskikh soedineniy s ispol'zovaniem neposredstvenno elementnogo fosfora v kachestve al'ternativnogo fosforiliruyushchego reagenta, minuya stadii ego galogenirovaniya. Tsel'yu nashey raboty yavlyaetsya razrabotka i razvitie novykh udobnykh metodov sinteza fosfororganicheskikh soedineniy s ispol'zovaniem krasnogo fosfora i generiruemogo iz nego fosfina. Na primere gidrosul'fid- i alkantiolat-anionov vpervye pokazano, chto serotsentrirovannye nukleofily sposobny rasshcheplyat' makromolekulu krasnogo fosfora (Pn) v DMSO s obrazovaniem svyazey P-S. Polucheny novye fundamental'nye dannye o formirovanii R-S svyazi na osnove reaktsiy alkenov s fosfinom, generiruemym vmeste s vodorodom v sisteme Pn-KON-N2O-toluol. Ustanovleny zakonomernosti etikh reaktsiy, kotorye v zavisimosti ot prirody kratnoy svyazi i eksperimental'nykh usloviy protekayut po skheme nukleofil'nogo ili radikal'nogo prisoedineniya i privodyat k prakticheski vostrebovannym i defitsitnym vtorichnym i tretichnym fosfinam i fosfinkhal'kogenidam, vklyuchaya funktsional'nye.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
14 January 2015
Listed Since
08 February 2015

Barcode

No barcode data available

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