Trimetallic Nitride Template Endohedral Fullerene Derivatives: Synthesis, characterization and potential application in solar energy conversion - Image 1

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VDM Verlag Trimetallic Nitride Template Endohedral Fullerene Derivatives: Synthesis, characterization and potential application in solar energy conversion

Name: Trimetallic Nitride Template Endohedral Fullerene Derivatives: Synthesis, characterization and potential application in solar energy conversion
Brand: VDM Verlag
Price: 71.0 GBP
Availability: InStock

Organic Chemistry

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Among renewable energy sources, solar energy has the potential to meet the world's growing demand for energy in the future. Currently there are many research efforts to prepare materials for photovoltaics including organic molecules. Among them, fullerene derivatives have been identified as promising materials for the construction of plastic solar cells. In this work the preparation and electrochemical properties of donor-acceptor systems based on trimetallic nitride endohedral metallofullerenes (TNT-EMFs) for solar energy conversion is described. It was found that TNT-EMFs have an enhanced ability to stabilize charge separated states formed upon light irradiation when compared to empty cage fullerene analogues. Optimal conditions for preparing cyclopropanated Bingel-Hirsch derivaties of the most common TNT-EMFs were found. Novel D-A systems were prepared using this strategy and their electrochemical properties revealed that they form films by electro-oxidative polymerization. These films generate electrical current upon light irradiation. This work is a guideline for anyone interested in exploring the chemistry and electrochemical properties of these novel materials.

Product Specifications

Brand: VDM Verlag
Format: paperback
ASIN: 3639719824
Category: Books > Subjects > Science, Nature & Maths > Chemistry > Organic Chemistry
Domain: Amazon UK
Publication Date: 08 August 2014
Listed Since: 02 September 2014

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VDM Verlag Trimetallic Nitride Template Endohedral Fullerene Derivatives: Synthesis, characterization and potential application in solar energy conversion

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VDM Verlag Trimetallic Nitride Template Endohedral Fullerene Derivatives: Synthesis, characterization and potential application in solar energy conversion

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