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Effet d'irradiation par faisceau d'électrons sur les propriétés physiques des polymères: Effet d'irradiation par faisceau d'électrons sur les polymères conducteurs

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£47.00 £44.65 £45.59 £46.53 £47.47 £48.41 £49.35 28 July 2026 13 August 2026 30 August 2026 15 September 2026 02 October 2026
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Description

Il décrit la modification des propriétés physiques dans un film d'électrolyte polymère PVDF-HFP/LiClO4 (avec un rapport 90:10, PHL10) irradié par un faisceau d'électrons (EB) d'une énergie de 8 MeV. Le résultat FT-IR montre l'apparition de C=C par rupture de la liaison H, ce qui indique un processus de scission de la chaîne dû à l'effet de l'irradiation. La morphologie d'une surface profondément poreuse avec une forme intérieure creuse a été observée après irradiation et la diminution de la cristallinité a été confirmée par les analyses XRD et DSC. L'absorbance optique a augmenté en raison de la transition interbande des électrons de la bande de valence à la bande de conduction, ce qui a entraîné une diminution de la bande interdite optique de 3,49 eV pour les matériaux non irradiés à 2,64 eV à la dose de 120 kGy. Les paramètres diélectriques varient avec l'augmentation de la fréquence et de la température dans le film irradié. La conductivité électrique observée augmente par le mouvement segmentaire des ions chargés dû au processus de scission/réticulation de la chaîne et une conductivité électrique élevée d'environ 1,81x10-3 S/cm avec une stabilité électrochimique a été observée après irradiation. Ces résultats suggèrent que les films électrolytes polymères irradiés sont électrochimiquement actifs et adaptés aux piles lithium-ion.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
30 June 2022
Listed Since
01 July 2022

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