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ÉDITIONS UNIVERSITAIRES EUROPÉENNES Synthèse et caractérisation des conducteurs au lithium nanostructurés

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Description

Le but de ce travail était d’étudier l’influence de la nanostructuration sur les propriétés de transport de deux matériaux conducteurs par les ions lithium, la pérovskite LLTO (Li0.3La0.57TiO3) et le nasicon LATPO (Li1.3Al0.3Ti1.7(PO4)3). Une première partie importante a été consacrée au développement de méthodes de synthèse par chimie douce plus favorables à la préparation de poudres nanométriques : la voie sol-gel, la voie des complexes polymérisables, la synthèse hydro-solvothermale et la réalisation de microémulsions. Les matériaux obtenus ont été caractérisés par diffraction des rayons X, analyses thermiques et microscopies électroniques. La mise en forme des échantillons ainsi que leur densification ont également fait l’objet d’une étude approfondie. Finalement, les mesures de conductivités ioniques ont été réalisées par spectroscopie d’impédance. L’ensemble des résultats obtenus a ensuite été comparé à ce qui a déjà été observé et reporté dans la littérature pour les composés microstructurés de même formulation.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
14 June 2019
Listed Since
08 July 2019

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