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ÉDITIONS UNIVERSITAIRES EUROPÉENNES Nanocomposites Polyéthylène/POSS: Etude de l''organisation à l''état solide et de la mobilité des chaînes polymères dans des nanocomposites polyéthylène/POSS (Omn.Univ.Europ.)

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Description

Liées de façon covalente à des chaînes polymères, les nanoparticules POSS permettent l''obtention de matériaux nanocomposites hybrides organique/inorganique. Les nanocomposites polymère/POSS peuvent présenter un renfort important des propriétés mécaniques de la matrice polymère. Afin de mieux comprendre l''origine moléculaire de ce renfort, nous avons étudié l''effet des particules POSS sur l''organisation à l''état solide et la dynamique des chaînes polymères au sein d''une matrice semi-cristalline. Pour cela, nous avons considéré une série de copolymères PE-POSS, caractérisés par une large gamme de concentration en POSS. Le PE et le POSS ayant intrinsèquement tendance à cristalliser, les copolymères présentent des organisations à l''état solide complexes que nous avons caractérisés par l''utilisation combinée de la DSC, de la diffraction des rayons X et de la RMN en phase solide. Puis, nous nous sommes intéressés à la dynamique des chaînes de PE en phase amorphe et à l''évolution de celle-ci avec le taux de charge des nanocomposites. Enfin, nous avons également étudié, de façon sélective, la dynamique des segments de chaînes de PE situés au voisinage de la charge.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
27 October 2010
Listed Since
28 October 2010

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