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OmniScriptum Nouveaux phosphates d'éléments de transition: structure et propriétés: Synthèse et caractérisations de nouveaux phosphates de fer et de manganèse ... catalytiques et magnétiques (Omn.Univ.Europ.)

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Description

Cette thèse porte sur l'étude de phosphates d'éléments de transition, dont les structures à charpentes mixtes comportent des cavités pouvant accueillir des cations en insertion. La richesse structurale rencontrée au sein de cette famille de composés ouvre la voie à de nombreuses propriétés. Nous avons orienté nos recherches vers l'étude de systèmes A-M-P-O(-H) où A est un cation monovalent et M un élément de transition (si possible en valence mixte), ou de post transition dans le but d'obtenir de nouveaux matériaux en vue d'application en catalyse d'une part et pour l'étude des propriétés magnétiques d'autre part. Nous avons pu isoler onze nouvelles phases dont trois présentent une charpente originale. Les déterminations structurales ont été effectuées par diffraction des RX sur monocristal combinée à des études par diffraction des RX sur poudre et à des analyses EDS. L'étude des propriétés catalytiques pour une réaction de DeNOx via la NH3-SCR a été réalisée par spectroscopie IR "in situ" et "operando" couplée à la spectrométrie de masse pour un des phosphates de fer synthétisés. Les propriétés magnétiques de quatre des composés présentés dans ce manuscrit sont discutées.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
05 September 2010
Listed Since
07 September 2010

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