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Editions Universitaires Europeennes Synthèse et caractérisation de nouveaux matériaux de cathode pour PCFC

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Description

Dans le domaine des piles à combustible, différents groupes de recherche s'intéressent au développement de nouveaux systèmes capables de fonctionner à des températures intermédiaires de l'ordre de 400-600°C. L'une des technologies envisagées est basée sur l'utilisation d'électrolytes céramiques possédant une conduction protonique élevée (Protonic Ceramic Fuel Cell PCFC). A ce jour, un des grands problèmes à résoudre concerne les fortes surtensions observées notamment au niveau de la cathode, lors de polarisations. Le but des recherches ici présentées a été de concevoir de nouveaux matériaux de cathode pour pile PCFC ayant de bonnes propriétés de conduction mixte ionique et électronique ainsi qu'une activité catalytique élevée vis-à-vis de la réduction de l'oxygène, entre 400°C et 600°C. La première monocellule PCFC française a ainsi pu être élaborée, et surtout, ces travaux innovants ont conduit à la réalisation d'un nouveau type de monocellule PCFC ayant pour matériau de cathode la composition Pr2NiO4+?, et présentant de bonnes performances (densité de puissance de 100 mW/cm² à 600°C). About the Author Ingénieur de formation, le Dr. Julian Dailly est actuellement responsable scientifique de projet à l'Institut Européen de Recherche sur l'Energie (EDF-EIfER, Karlsruhe) sur des thématiques allant de l'élaboration et la mise en forme de matériaux céramiques aux mesures électrochimiques de cellules SOFC, SOEC et PCFC.

Product Specifications

Format
Paperback
Domain
Amazon UK
Release Date
15 July 2010
Listed Since
19 July 2010

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