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OmniScriptum Mécanismes de rétention du cuivre dans les sols: Evaluation statistique des approches macroscopiques et spectroscopiques (Omn.Pres.Franc.)

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Description

Le cuivre est un élément chimique, nocif pour la matière vivante, qui peut s'associer sous de nombreuses formes aux constituants organiques et inorganiques des sols. A une échelle macroscopique, les modélisations thermodynamiques, sont insuffisantes pour conclure sur la nature des formes présentes. La μ-spectroscopie d'absorption X permet d'accéder à cette information. A cette échelle micrométrique, la variabilité spécifique des formes du cuivre d'un point d'analyse à un autre se traduit par un changement du signal mesuré. L'Analyse en Composantes Principales (ACP) permet alors en théorie de dénombrer les espèces pures. Ces techniques ont été utilisées pour caractériser les formes cuprifères d'une part dans des rizières contaminées par une exploitation minière et d'autre part dans un bassin d'infiltration d'eaux de ruissellement. Les présences de cuivre associé avec la matière organique et sous formes de cristaux localement spécifiques ont été mises en évidence. Mais, en raison de la faible fiabilité des indicateurs existants, le nombre total des espèces n'a pu être que majoré par ACP. Ce problème a été surmonté par la mise au point d'un nouvel indicateur évalué statistiquement.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
23 November 2012
Listed Since
28 November 2012

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