£67.00

Polylysin als Flockungshilfsmittel Stimuli-responsive Porenmembranen: Poly-L-Lysin als bioabbaubares Flockungshilfsmittel und als Baustein für stimuli-responsive Porenmembranen

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Description

Einerseits sollten Polylysin Homopolymere im Hinblick auf den Einsatz als biologisch abbaubare Flockungshilfsmittel in Fest-Flüssig Trennungsprozessen synthetisiert werden. Anderseits sollte die Pfropfung des Polylysins durch die aminintiierte Ringöffnungspolymerisation des ?-N-Benzyloxycarbonyl-L-Lysin-N-Carbonsäureanhydrids und die Stimuli-Responsivität des gepfropften Polymers untersucht werden. Anwendungstechnische Untersuchungen wie Jar-Test, Schlammvolumenindex und bestimmund des CST-Wertes wurden zur Testen der Flockulationseigenschaften und zur Testen der Verbesserung der Absätzbarkeit der Schlämme durchgeführt. Die biologische Abbaubarkeit wurde nach DIN EN ISO 9888, untersucht. Durch Pfropfung von Poly-?-N-Benzyloxycarbonyl-L-Lysin auf der PET Membranoberfläche via "Grafting-from" Ringöffnungspolymerisation wurden die PET-Membranen erfolgreich modifiziert. Die Messungen der Permeabilitäten mit Lösungen unterschiedlicher pH-Werte und mit Salzlösungen unterschiedlicher Konz. haben die Schaltbarkeit des gepfropften Poly-L-Lysins nachgewiesen. Die Porenöffnung bzw. Porenschliessung könnte einer Änderung der Konformation des gepfropften Polymers zugeordnet werden.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
29 November 2010
Listed Since
30 November 2010

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