£57.00

EAE Editorial Academia Espanola Hidroformilación de Olefinas con Complejos de Cobalto: Síntesis, Caracterización y Pruebas Catalíticas de Complejos de Cobalto Sustituidos con Ligandos carbonilos y Fosfinas

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Description

Se sintetizaron tres complejos de cobalto, el octacarbonilo de dicobalto y dos complejos del tipo Hexacarbonil bistrialquilfosfina de dicobalto (donde R fueron tri-butilfosfina y trifenilfosfina respectivamente). El primer complejo se sintetizó usando el método de síntesis a alta presión. Los dos complejos con ligandos CO sustituidos por las fosfinas, se sintetizaron a partir del primero mediante una síntesis en solución no acuosa. Una vez sintetizados todos los complejos, fueron caracterizados empleando las técnicas de espectroscopía infrarroja, espectrometría de masas y espectroscopía UV/Vis. Los complejos sintetizados fueron usados como precursores catalíticos en pruebas puntuales de hidroformilación usando como sustrato modelo el 1-hexeno. Se optimizaron las condiciones de temperatura, tiempo, presión y relación sustrato-catalizador y se probaron otros sustratos con el fin de establecer comparaciones entre la actividad catalítica de cada especie.

Product Specifications

Format
paperback
Domain
Amazon UK
Release Date
20 June 2013
Listed Since
27 October 2013

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