£43.63

Springer Komplexbildung in Lösung: Methoden zur Bestimmung der Zusammensetzung und der Stabilitätskonstanten gelöster Komplexverbindungen (Molekülverbindungen ... in Einzeldarstellungen)

black & white illustrations, bibliograph

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Description

In den letzten zwei Dezennien hat die Chemie der Koordinations verbindungen durch die zunehmende Anwendung moderner physikalisch chemischer Untersuchungsmethoden bedeutsame Fortschritte gemacht. Es sei als Beispiel an die experimentelle und theoretische Erforschung der Lichtabsorptionseigenschaften von Komplexverbindungen erinnert, die zu einer prinzipiellen AufkHirung des Problems Farbe und Konsti tution gefiihrt hat. So hat man auch die Gleichgewichte in Lasungen von Komplexionen - insbesondere in waBrigen Lasungen -systematisch studiert. Die verschiedenen Methoden zur Untersuchung der Komplex bildung in Lasung stellen heute ein wichtiges Sondergebiet der Koordi nationschemie dar. Wesentlich gefardert durch die grundlegenden Arbeiten von J. BJERRuM, besonders durch dessen im Jahre 1941 er schienene Dissertation "Metal ammine formation in aqueous solution" sind seitdem zahlreiche Komplexbildungsgleichgewichte untersucht worden. Die Kenntnis der in Lasungen unter bestimmten Bedingungen vor liegenden Typen von Metallkomplexen, ihrer Stabilitatskonstanten und ihrer Existenzbereiche ist nicht nur von rein wissenschaftlichem, sondern auch dariiber hinaus von erheblichem praktischen Interesse. In vielen Gebieten der Chemie, wie z. B. der analytischen Chemie, der Biochemie, der Gerbereichemie, der Homogenkatalyse, als Zwischenverbindungen bei organischen Synthesen und bei den modernen radiochemischen Methoden spielen Komplexverbindungen in Lasung eine wesentliche Rolle.

Product Specifications

Format
paperback
Domain
Amazon UK
Publication Date
10 April 2012
Listed Since
17 April 2014

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