Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses) - Image 1

£76.38

Springer Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses)

Name: Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses)
Brand: Springer
Price: 76.38 GBP
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Biochemistry

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Description

This thesis presents the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. It also details a biomimetic method for converting Plakortide E methyl ester to plakortone B. From the Back Cover In his thesis, Xiao-yu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiao-yu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and functionalization of cyclic peroxides are notoriously difficult due to the very low O-O bond dissociation energy. Plaktoride E is isolated from the Jamaican marine sponge platorits halichondrioides and contains a five-membered peroxide ring, with oxygen atoms linked to tertiary C4 and C6 centers. The methodology used for synthesizing highly substituted cyclic peroxides is novel and useful, and not only extends the field of Pd-catalyzed reactions, but also provides a convenient synthetic approach for the preparation of the 1,2-dioxolanes series. Plakortide E and plakortone B are bioactive, which means that the synthetic studies on them and their analogs are pivotal in drug discovery.

Product Specifications

Brand: Springer
Format: paperback
ASIN: 3642442110
Category: Books > Subjects > Science, Nature & Maths > Biological Sciences > Biochemistry
Domain: Amazon UK
Publication Date: 22 February 2014
Listed Since: 13 February 2014

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Springer Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses)

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