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Springer Late Transition Metal-Carboryne Complexes: Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes (Springer Theses)

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Description

This ground-breaking new work in metal-carboryne chemistry shows how transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. From the Back Cover In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molecules in a single operation from very simple precursors. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and until now limited efficient synthetic methods to obtain functional carborane materials have restricted their application. This work breaks new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.

Product Specifications

Format
paperback
Domain
Amazon UK
Publication Date
22 February 2014
Listed Since
13 February 2014

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