Zakonomernosti sinteza poliefirketonov i poliefirsul'fonov: Monografiya - Image 1

£45.00

VDM Verlag Zakonomernosti sinteza poliefirketonov i poliefirsul'fonov: Monografiya

Name: Zakonomernosti sinteza poliefirketonov i poliefirsul'fonov: Monografiya
Brand: VDM Verlag
Price: 45.0 GBP
Availability: InStock

Organic Chemistry

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Description

V rabote izucheny kineticheskie zakonomernosti reaktsii sinteza prostykh aromaticheskikh poliefirov na osnove fenolftaleina i 4,4-dikhlordifenilsul'fona, ob"yasnyayushchie osobennosti eye protekaniya, kinetika reaktsii vzaimodeystviya diana s "aktivirovannymi" aromaticheskimi 4,4-digalogenproizvodnymi, soderzhashchimi razlichnye mostikovye gruppy ili razlichnye galogeny. Ustanovlena vozmozhnost' obrazovaniya gomo- i geterokoordinatsionnykh sistem v srede DMSO–digalogenaren – difeno-ksidnyy anion, vliyayushchikh na reaktsionnuyu sposobnost' iskhodnykh monomerov i snizhayushchikh skorost' reaktsii. Predlozhen mekhanizm aromaticheskogo nukleofil'nogo zameshcheniya pri sinteze prostykh aromaticheskikh poliefirov na osnove 4,4-digalogendifenilketona s uchetom protekaniya pobochnykh reaktsiy obrazovaniya koordinatsionnykh sistem. Pokazana vozmozhnost' polucheniya digidroksilsoderzhashchego "dimera" pri vzaimodeystvii v DMSO 4,4-dikhlordifenilketona s difenolyatom diana v sootnoshenii 1:2. Na osnove sintezirovannogo "dimera" predlozhena skhema i osushchestvlen sintez novykh aromaticheskikh sopoliefirketonov: poliarilenefirketonsul'fonov (PAEKS), poliarilenefirketonformaley (PAEKF), poliarilenefiroketonsul'fonformaley (PAEKSF), poliarilenefirketonarilatov(PAEKA).

Product Specifications

Brand: VDM Verlag
Format: paperback
ASIN: 3639735056
Category: Books > Subjects > Science, Nature & Maths > Chemistry > Organic Chemistry
Domain: Amazon UK
Publication Date: 04 March 2014
Listed Since: 07 March 2014

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VDM Verlag Zakonomernosti sinteza poliefirketonov i poliefirsul'fonov: Monografiya

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