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VDM Verlag Refinamiento estructural en hexacianoferratos: Fenómenos térmicamente inducidos y propiedades magnéticas asociadas

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Description

El libro contiene el refinamiento estructural de quince hexacianoferratos (II, III), donde doce estructuras cristalinas se reportan por primera vez. Además, se analiza la distorsión ortorrómbica que aparece en algunas de las estructuras debido a la influencia de los cationes de compensación de carga presentes en las mismas. También se analiza el efecto del tratamiento térmico sobre la estructura y las propiedades magnéticas de los hexacianoferratos (III) de M2+ (M=Zn, Ni, Mn y Cu) y de los hexacianoferrato (III) de Co2+; reportándose una transferencia interna de carga del Co2+ hacia el FeIII que provoca la formación de una solución sólida con estados de valencia mixta. Como parte del estudio, también se analiza el papel que juega el agua estructural en el comportamiento magnético de los materiales.

Product Specifications

Format
paperback
Domain
Amazon UK
Publication Date
02 March 2014
Listed Since
03 March 2014

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