Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (Springer Theses) - Image 1

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Springer Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (Springer Theses)

Name: Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (Springer Theses)
Brand: Springer
Price: 108.01 GBP
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Inorganic Chemistry

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Description

This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon–carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, andhighlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C–H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.

Product Specifications

Brand: Springer
Format: paperback
ASIN: 3030540790
Category: Books > Subjects > Science, Nature & Maths > Chemistry > Inorganic Chemistry
Domain: Amazon UK
Release Date: 03 September 2021
Listed Since: 09 August 2021

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Springer Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (Springer Theses)

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