Wiley Relativistic Effects in Heavy-Element Chemistry and Physics (Wiley Series in Theoretical Chemistry)

Heavy atoms and their compounds are important in many areas ofmodern technology. Their versatility in the reactions they undergois the reason that they can be found in most homogeneous andheterogeneous catalysts. Their magnetism is the decisive propertythat qualifies them as materials for modern storage devices. The phenomena observed in compounds of heavy atoms such asphosphorescence, magnetism or the tendency for high valency inchemical reactions can to a large extent be traced back torelativistic effects in their electronic structure. Thus, in manyaspects relativistic effects dominate the physics and chemistry ofheavy atoms and their compounds. Chemists are usually aware of these phenomena, however, the theorybehind them is not part of the standard chemistry curriculum andthus not widely known among experimentalists. Whilst therelativistic quantum theory of electronic structure is wellestablished in physics, applications of the theory to chemicalsystems and materials have been feasible only in the last decadeand their practical applications in connection with chemicalexperiment is somewhat out of sight of modern theoretical physics. Relativistic Effects in Heavy Element Chemistry and Physicsintends to bridge the gap between chemistry and physics on the onehand and between theory and experiment on the other. Topics covered include: A broad range from quantum electrodynamics to the phenomenology ofthe compounds of heavy and superheavy elements A state-of-the-art survey of the most important theoreticaldevelopments and applications in the field of relativistic effectsin heavy-element chemistry and physics in the last decade Special emphasis on the work of researchers in Europe and Germanyin the framework of research programmes of the European ScienceFoundation and the German Science Foundation